What's the difference between thermoset plastics and thermoplastics?

Thermoplastics and thermoset plastics are commonly used in injection molding, and each of the two have their own unique advantages.

What’s the Difference?

  1. Thermoset Plastics: Linked by covalent bonds; undergo curing process during heating and shaping which causes permanent chemical change in molecular structure. Common materials include epoxy, silicone, polyurethane.

    (TLDR; material remains in a permanent solid state after being cured once).

  2. Thermoplastics: Linked by Van der Waals bonds; can be heated and reheated, reversible plastic operation

Advantages/Disadvantages:

Thermoplastics

  • Advantages

    • Commonly used for aesthetic surface finishes
    • Recylability, end plastic part can be re-melted and formed into different shapes (commonly ued for toys, furniture, etc.)
  • Disadvantages

    • Ineffective for parts regularly exposed to extreme heat or rapidly varying temperature ranges as they can melt more easily
    • Molding process requires higher heat and pressure to create parts

Thermoset Plastics

  • Advantages

    • Generally do not melt when exposed to heat
    • Do not deform, warp, or lose shape in varying temp. ranges
    • Molding process is cheaper as they require less complex tooling (i.e. far less heat and pressure)
  • Disadvantages

    • Much more difficult to surface finish
    • Cannot be remolded or reshaped
    • Poor thermal conductivity and rigidity